Hydrogel Patterning with Catechol Enables Networked Electron Flow
نویسندگان
چکیده
Reduction–oxidation (redox) reactions provide a distinct modality for biological communication that is fundamentally different from the more-familiar ion-based electrical modality. Biology uses these two modalities through systems (immune versus nervous), and mechanisms to control flow of charge carriers: soluble ions controlled using structural barriers (i.e., membranes) gates (e.g., membrane-spanning protein channels), while insoluble electrons redox-reaction networks. Here, simple electrochemical approach pattern catechols onto flexible polysaccharide hydrogel reported it demonstrated patterned catechol regions serve as nodes mediated redox reactions. Electron this node involves switching binary states (oxidized reduced) node's state can be detected “read”) by passively observing its optical absorbance, or actively redox-state electrochemically. Further, switched mechanisms, enables fabricated embedded within biochemical reaction networks facilitate spanning bio-electronic communication. Thus, envisioned emerge molecular equivalent transistor miniaturize-able, deployable sustainable redox-linked bioelectronics.
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ژورنال
عنوان ژورنال: Advanced Functional Materials
سال: 2021
ISSN: ['1616-301X', '1616-3028']
DOI: https://doi.org/10.1002/adfm.202007709